As someone else pointed out, nitrogen is non-reactive. Almost any gas would work, as long as it was plentiful enough to maintain the necessary air pressure, and non-reactive. You don’t need nitrogen to live; you just need oxygen. Just, not so much that you get acute oxygen toxicity, which mainly happens with pure oxygen at regular atmospheric pressure for extended periods of time. There are even applications where pure oxygen is administered to people, usually at lower than atmospheric pressure.
Nitrogen is a filler gas. It’s there to take up space and keep the air molecules bouncing around at the appropriate pressure. (Or perhaps it would be more accurate to say our lungs require a certain pressure because this is where we evolved; that pressure happens to be maintained mostly by nitrogen.)
We aren’t exploring other planets in person yet, but if we were, we’d need to filter out all the bad shit in the air, keep the oxygen, and maintain the normal pressure. If we were lucky enough to encounter an atmosphere with oxygen, a non-reactive filler gas, and no toxins, we might be able to just breathe it; or to breathe it after compressing it to the appropriate pressure. Nitrogen wouldn’t need to be there at all.
The confusing thing about the scuba application is that nitrogen isn’t in the mix because you need the nitrogen. It’s there because it reduces the pressure of toxic gases to a threshhold you can survive.